Short answer: Yes. It possible to teach someone Logic who just knows Natural Language.
I agree with @haxor789 and @Mauro ALLEGRANZA. They both point to humans essentially/naturally/necessarily being logical in nature.
Premise 1: Humans are Logical Beings.
One can make the argument that every action (action, thought, communication, belief, etc.) is a logical or a logical argument. Although we don't normally see such regular actions (like a child playing with a toy) through the lens of logic, it can be viewed when analyzing. This can be supported through analyzing a child's decisions in play therapy. Why did the child place a specific toy being a fence? Was it an indication that the child feels guarded? Prior to clear decision making and preferences, babies cry, and, at least from my experience, it is a sign/consequence of something else: hunger, dirty diaper, boo-boo, etc. This would be in the form of "If A, then B. A exists, therefore B." If hungry, then cry. I'm hungry, therefore I cry.
Premise 2: Logic as a "Form."
I would also argue that logic itself can be comparable to Aristotle's (and others) concept of forms. A form is the essence or defining characteristic of a thing, explaining what it is. Although there are surely other and better definitions, the form of logic would be " a tool for understanding and evaluating the world (and beyond) around us." Logic as we speak of and use here is the mode/language we use to communicate and rationalize the world around us. The form of a chair exists, but how we build chair and what it looks like is more physical and personal. Logic is like the chair.
Premise 3: Natural Language (and all Language) is the Embodiment of the "Form" of Logic.
Logic exists and we need a way to conceptualize it and communicate it with others. First-order Logic (FOL) is one language that has been created to express the "form" of logic. However, any language can be used to express the "form" of logic. As used above, English can be used as an expression of logic: "If hungry, then cry. I'm hungry, therefore I cry." The natural language the person uses shouldn't matter either (although I would love to study if there is a connection between what language a person utilizes in their life and its effect on their beliefs).
Whether its FOL or English or any other language, I would argue that it embodies the "form" of logic. Natural Language is the chair a person builds, and Logic is the "form" of the chair.
Conclusion: English, or any language, can be used to teach logic because English, or any language, is the expression of the "form" of logic.
Hot take: English is not a good language for expressing logic, and certainly not the best.
My problem with the English language is how many implied premises there must be in order for it to be effective. I could say, "I love __________." The definition of "love" as used here in English would be entirely dependent on the context or the predicate of the sentence. The logic expressed in another language (or translated) would need to add an implied premise, being the context. I love my wife much differently than I love Oreos. There would be many implied premises to the argument to differentiate the kind of love used. English really uses just love, whereas Greek has many. In Greek, there are multiple words for "love," each capturing a distinct aspect of the concept, the main ones I can think of are: Agápe (Αγάπη); Éros (Έρως); Philía (Φιλία); Storgē (Στοργή); Xenía (Ξενία); and Manía (Μανία).
I would conclude that while English can be used to teach and express logic, it is not the best to do so.